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Practical and economic lithiations of functionalized arenes and heteroarenes using Cy(2)NLi in the presence of Mg, Zn or La halides in a continuous flow
The economic amide base lithium dicyclohexylamide (Cy(2)NLi) allows fast and convenient (40 s, 0 °C) in situ trapping flow metalations of a broad range of functionalized arenes, heteroarenes and acrylate derivatives in the presence of various metal salts (ZnCl(2)·2LiCl, MgCl(2), LaCl(3)·2LiCl). The...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2015
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5802273/ https://www.ncbi.nlm.nih.gov/pubmed/29435214 http://dx.doi.org/10.1039/c5sc02558c |