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N-Heterocycle-Ligated Borocations as Highly Tunable Carbon Lewis Acids
[Image: see text] The relative (to BEt(3)) hydride ion affinity (HIA) of a series of acridine borenium salts has been calculated, with some HIAs found to be similar to that for [Ph(3)C](+). The HIA at the acridine C9 position is controlled by both acridine and the boron substituents, the latter pres...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American
Chemical Society
2017
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5803673/ https://www.ncbi.nlm.nih.gov/pubmed/29430073 http://dx.doi.org/10.1021/acs.organomet.7b00779 |