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N-Heterocycle-Ligated Borocations as Highly Tunable Carbon Lewis Acids

[Image: see text] The relative (to BEt(3)) hydride ion affinity (HIA) of a series of acridine borenium salts has been calculated, with some HIAs found to be similar to that for [Ph(3)C](+). The HIA at the acridine C9 position is controlled by both acridine and the boron substituents, the latter pres...

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Detalles Bibliográficos
Autores principales: Radcliffe, James E., Dunsford, Jay J., Cid, Jessica, Fasano, Valerio, Ingleson, Michael J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2017
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5803673/
https://www.ncbi.nlm.nih.gov/pubmed/29430073
http://dx.doi.org/10.1021/acs.organomet.7b00779