A family of N-heterocyclic carbene-stabilized borenium ions for metal-free imine hydrogenation catalysis

This manuscript probes the steric and electronic attributes that lead to “frustrated Lewis pair” (FLP)-type catalysis of imine hydrogenation by borenium ions. Hydride abstraction from (ItBu)HB(C(6)F(5))(2)2 prompts intramolecular C–H bond activation to give (CHN)(2)(tBu) (CMe(2)CH(2))CB(C(6)F(5))(2)...

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Detalles Bibliográficos
Autores principales: Farrell, Jeffrey M., Posaratnanathan, Roy T., Stephan, Douglas W.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2015
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5810240/
https://www.ncbi.nlm.nih.gov/pubmed/29449920
http://dx.doi.org/10.1039/c4sc03675a

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5810240/
https://www.ncbi.nlm.nih.gov/pubmed/29449920
http://dx.doi.org/10.1039/c4sc03675a

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