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A family of N-heterocyclic carbene-stabilized borenium ions for metal-free imine hydrogenation catalysis
This manuscript probes the steric and electronic attributes that lead to “frustrated Lewis pair” (FLP)-type catalysis of imine hydrogenation by borenium ions. Hydride abstraction from (ItBu)HB(C(6)F(5))(2)2 prompts intramolecular C–H bond activation to give (CHN)(2)(tBu) (CMe(2)CH(2))CB(C(6)F(5))(2)...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2015
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5810240/ https://www.ncbi.nlm.nih.gov/pubmed/29449920 http://dx.doi.org/10.1039/c4sc03675a |