Dehydrogenation of formic acid by Ir–bisMETAMORPhos complexes: experimental and computational insight into the role of a cooperative ligand

The synthesis and tautomeric nature of three xanthene-based bisMETAMORPhos ligands (La–Lc) is reported. Coordination of these bis(sulfonamidophosphines) to Ir(acac)(cod) initially leads to the formation of Ir(I)(L (H)) species (1a), which convert via formal oxidative addition of the ligand to Ir(III...

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Detalles Bibliográficos
Autores principales: Oldenhof, Sander, Lutz, Martin, de Bruin, Bas, Ivar van der Vlugt, Jarl, Reek, Joost N. H.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2015
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5811074/
https://www.ncbi.nlm.nih.gov/pubmed/29560190
http://dx.doi.org/10.1039/c4sc02555e

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5811074/
https://www.ncbi.nlm.nih.gov/pubmed/29560190
http://dx.doi.org/10.1039/c4sc02555e

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