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The effect of host structure on the selectivity and mechanism of supramolecular catalysis of Prins cyclizations

The effect of host structure on the selectivity and mechanism of intramolecular Prins reactions is evaluated using K(12)Ga(4)L(6) tetrahedral catalysts. The host structure was varied by modifying the structure of the chelating moieties and the size of the aromatic spacers. While variation in chelato...

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Detalles Bibliográficos
Autores principales: Hart-Cooper, William M., Zhao, Chen, Triano, Rebecca M., Yaghoubi, Parastou, Ozores, Haxel Lionel, Burford, Kristen N., Toste, F. Dean, Bergman, Robert G., Raymond, Kenneth N.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5811099/
https://www.ncbi.nlm.nih.gov/pubmed/29560226
http://dx.doi.org/10.1039/c4sc02735c