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Orthoester exchange: a tripodal tool for dynamic covalent and systems chemistry

Reversible covalent reactions have become an important tool in supramolecular chemistry and materials science. Here we introduce the acid-catalyzed exchange of O,O,O-orthoesters to the toolbox of dynamic covalent chemistry. We demonstrate that orthoesters readily exchange with a wide range of alcoho...

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Detalles Bibliográficos
Autores principales: Brachvogel, René-Chris, von Delius, Max
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5811105/
https://www.ncbi.nlm.nih.gov/pubmed/29560228
http://dx.doi.org/10.1039/c4sc03528c