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Molecular recognition in curved π-systems: effects of π-lengthening of tubular molecules on thermodynamics and structures

The thermodynamics and molecular structure of a supramolecular complex between a tubular molecule, (P)-(12,8)-[4]cyclo-2,8-anthanthrenylene, and fullerene were investigated. The enthalpy-driven characteristics of the association were enhanced upon lengthening of the curved sp(2)-carbon networks in t...

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Detalles Bibliográficos
Autores principales: Matsuno, Taisuke, Sato, Sota, Iizuka, Ryosuke, Isobe, Hiroyuki
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5811110/
https://www.ncbi.nlm.nih.gov/pubmed/29560176
http://dx.doi.org/10.1039/c4sc02812k