Topochemical conversion of a dense metal–organic framework from a crystalline insulator to an amorphous semiconductor

The topochemical conversion of a dense, insulating metal–organic framework (MOF) into a semiconducting amorphous MOF is described. Treatment of single crystals of copper(i) chloride trithiocyanurate, Cu(I)Cl(ttcH(3)) (ttcH(3) = trithiocyanuric acid), 1, in aqueous ammonia solution yields monoliths o...

Descripción completa

Detalles Bibliográficos
Autores principales: Tominaka, S., Hamoudi, H., Suga, T., Bennett, T. D., Cairns, A. B., Cheetham, A. K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2015
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5811114/
https://www.ncbi.nlm.nih.gov/pubmed/29560235
http://dx.doi.org/10.1039/c4sc03295k

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5811114/
https://www.ncbi.nlm.nih.gov/pubmed/29560235
http://dx.doi.org/10.1039/c4sc03295k

Ejemplares similares