Cargando…
Tandem redox mediator/Ni(ii) trihalide complex photocycle for hydrogen evolution from HCl
Photoactivation of M–X bonds is a challenge for photochemical HX splitting, particularly with first-row transition metal complexes because of short intrinsic excited state lifetimes. Herein, we report a tandem H(2) photocycle based on combination of a non-basic photoredox phosphine mediator and nick...
| Autores principales: | , , , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2015
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5811117/ https://www.ncbi.nlm.nih.gov/pubmed/29560177 http://dx.doi.org/10.1039/c4sc02357a |