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Tandem redox mediator/Ni(ii) trihalide complex photocycle for hydrogen evolution from HCl
Photoactivation of M–X bonds is a challenge for photochemical HX splitting, particularly with first-row transition metal complexes because of short intrinsic excited state lifetimes. Herein, we report a tandem H(2) photocycle based on combination of a non-basic photoredox phosphine mediator and nick...
Autores principales: | Hwang, Seung Jun, Powers, David C., Maher, Andrew G., Nocera, Daniel G. |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Royal Society of Chemistry
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5811117/ https://www.ncbi.nlm.nih.gov/pubmed/29560177 http://dx.doi.org/10.1039/c4sc02357a |
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