Cargando…

Tandem redox mediator/Ni(ii) trihalide complex photocycle for hydrogen evolution from HCl

Photoactivation of M–X bonds is a challenge for photochemical HX splitting, particularly with first-row transition metal complexes because of short intrinsic excited state lifetimes. Herein, we report a tandem H(2) photocycle based on combination of a non-basic photoredox phosphine mediator and nick...

Descripción completa

Detalles Bibliográficos
Autores principales: Hwang, Seung Jun, Powers, David C., Maher, Andrew G., Nocera, Daniel G.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5811117/
https://www.ncbi.nlm.nih.gov/pubmed/29560177
http://dx.doi.org/10.1039/c4sc02357a

Ejemplares similares