Cargando…
The boron–boron triple bond? A thermodynamic and force field based interpretation of the N-heterocyclic carbene (NHC) stabilization procedure
Recently, the NHC→B[triple bond, length as m-dash]B←NHC molecule 1 has been published in Science where it is described as a stabilized B(2) molecule in its (1)Σ excited state (B(2)*) (NHC = N-heterocyclic carbene C(3)N(2)H(2)(C(6)H(3)Pr(i)(2)-2,6)(2)). The bonding of 1 based on sophisticated calcula...
| Autores principales: | , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2015
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5811121/ https://www.ncbi.nlm.nih.gov/pubmed/29560205 http://dx.doi.org/10.1039/c4sc02997f |