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Synthesis of arsenic-rich As(n) ligand complexes from yellow arsenic

The reaction of [{η(5)-Cp′′′Co}(2){μ,η(4:4)-toluene}] with yellow arsenic yields the arsenic-rich As(n) ligand complexes [{Cp′′′Co(μ,η(2:2)-As(2))}(2)] (1), [(Cp′′′Co)(4)(μ(4),η(4:4:2:2:1:1)-As(10))] (2) and [(Cp′′′Co)(3)(μ(3),η(4:4:2:1)-As(12))] (3), which were comprehensively characterized. The mo...

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Detalles Bibliográficos
Autores principales: Graßl, C., Bodensteiner, M., Zabel, M., Scheer, M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5811125/
https://www.ncbi.nlm.nih.gov/pubmed/29560225
http://dx.doi.org/10.1039/c4sc03543g