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Synthesis of arsenic-rich As(n) ligand complexes from yellow arsenic
The reaction of [{η(5)-Cp′′′Co}(2){μ,η(4:4)-toluene}] with yellow arsenic yields the arsenic-rich As(n) ligand complexes [{Cp′′′Co(μ,η(2:2)-As(2))}(2)] (1), [(Cp′′′Co)(4)(μ(4),η(4:4:2:2:1:1)-As(10))] (2) and [(Cp′′′Co)(3)(μ(3),η(4:4:2:1)-As(12))] (3), which were comprehensively characterized. The mo...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2015
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5811125/ https://www.ncbi.nlm.nih.gov/pubmed/29560225 http://dx.doi.org/10.1039/c4sc03543g |