Synthesis, structure, and reactivity of crystalline molecular complexes of the {[C(5)H(3)(SiMe(3))(2)](3)Th}(1–) anion containing thorium in the formal +2 oxidation state

Reduction of the Th(3+) complex Cp′′3Th, 1 [Cp′′ = C(5)H(3)(SiMe(3))(2)], with potassium graphite in THF in the presence of 2.2.2-cryptand generates [K(2.2.2-cryptand)][Cp′′3Th], 2, a complex containing thorium in the formal +2 oxidation state. Reaction of 1 with KC(8) in the presence of 18-crown-6...

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Detalles Bibliográficos
Autores principales: Langeslay, Ryan R., Fieser, Megan E., Ziller, Joseph W., Furche, Filipp, Evans, William J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2015
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5811171/
https://www.ncbi.nlm.nih.gov/pubmed/29560172
http://dx.doi.org/10.1039/c4sc03033h

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5811171/
https://www.ncbi.nlm.nih.gov/pubmed/29560172
http://dx.doi.org/10.1039/c4sc03033h

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