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Ultra‐Fast Molecular Rotors within Porous Organic Cages

Using variable temperature (2)H static NMR spectra and (13)C spin‐lattice relaxation times (T(1)), we show that two different porous organic cages with tubular architectures are ultra‐fast molecular rotors. The central para‐phenylene rings that frame the “windows” to the cage voids display very rapi...

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Detalles Bibliográficos
Autores principales: Hughes, Ashlea R., Brownbill, Nick J., Lalek, Rachel C., Briggs, Michael E., Slater, Anna G., Cooper, Andrew I., Blanc, Frédéric
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5813266/
https://www.ncbi.nlm.nih.gov/pubmed/29053892
http://dx.doi.org/10.1002/chem.201704964