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π-Electron systems containing Si=Si double bonds

Sterically large substituents can provide kinetic stabilization to various types of low-coordinate compounds. For example, regarding the chemistry of the group 14 elements, since West et al. introduced the concept of kinetic protection of the otherwise highly reactive Si=Si double bond by bulky mesi...

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Detalles Bibliográficos
Autores principales: Matsuo, Tsukasa, Hayakawa, Naoki
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Taylor & Francis 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5814778/
https://www.ncbi.nlm.nih.gov/pubmed/29467912
http://dx.doi.org/10.1080/14686996.2017.1414552