Binding of Hydrophobic Guests in a Coordination Cage Cavity is Driven by Liberation of “High‐Energy” Water

The cavity of an M(8)L(12) cubic coordination cage can accommodate a cluster of ten water molecules in which the average number of hydrogen bonds per water molecule is 0.5 H‐bonds less than it would be in the bulk solution. The presence of these “hydrogen‐bond frustrated” or “high‐energy” water mole...

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Detalles Bibliográficos
Autores principales: Metherell, Alexander J., Cullen, William, Williams, Nicholas H., Ward, Michael D.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2017
Materias:
Full Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5814853/
https://www.ncbi.nlm.nih.gov/pubmed/29083066
http://dx.doi.org/10.1002/chem.201704163

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5814853/
https://www.ncbi.nlm.nih.gov/pubmed/29083066
http://dx.doi.org/10.1002/chem.201704163

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