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Teaching Old Compounds New Tricks: DDQ‐Photocatalyzed C−H Amination of Arenes with Carbamates, Urea, and N‐Heterocycles

The C−H amination of benzene derivatives was achieved using DDQ as photocatalyst and BocNH(2) as the amine source under aerobic conditions and visible light irradiation. Electron‐deficient and electron‐rich benzenes react as substrates with moderate to good product yields. The amine scope of the rea...

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Detalles Bibliográficos
Autores principales: Das, Somnath, Natarajan, Palani, König, Burkhard
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5814878/
https://www.ncbi.nlm.nih.gov/pubmed/29143992
http://dx.doi.org/10.1002/chem.201705442