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Syn-selective silicon Mukaiyama-type aldol reactions of (pentafluoro-λ(6)-sulfanyl)acetic acid esters with aldehydes

Aldol reactions belong to the most frequently used C–C bond forming transformations utilized particularly for the construction of complex structures. The selectivity of these reactions depends on the geometry of the intermediate enolates. Here, we have reacted octyl pentafluoro-λ(6)-sulfanylacetate...

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Detalles Bibliográficos
Autores principales: Dreier, Anna-Lena, Matsnev, Andrej V, Thrasher, Joseph S, Haufe, Günter
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5815270/
https://www.ncbi.nlm.nih.gov/pubmed/29507642
http://dx.doi.org/10.3762/bjoc.14.25