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(17)O solid-state NMR spectroscopy of A(2)B(2)O(7) oxides: quantitative isotopic enrichment and spectral acquisition?

The potential of (17)O NMR spectroscopy for the investigation of A(2)B(2)O(7) ceramic oxides important in the encapsulation of radioactive waste is demonstrated, with post-synthetic enrichment by exchange with (17)O(2) gas. For Y(2)Sn(2)O(7), Y(2)Ti(2)O(7) and La(2)Sn(2)O(7) pyrochlores, enrichment...

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Detalles Bibliográficos
Autores principales: Fernandes, Arantxa, Moran, Robert F., Sneddon, Scott, Dawson, Daniel M., McKay, David, Bignami, Giulia P. M., Blanc, Frédéric, Whittle, Karl R., Ashbrook, Sharon E.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5815285/
https://www.ncbi.nlm.nih.gov/pubmed/29568509
http://dx.doi.org/10.1039/c8ra00596f