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1‐Alkali‐metal‐2‐alkyl‐1,2‐dihydropyridines: Soluble Hydride Surrogates for Catalytic Dehydrogenative Coupling and Hydroboration Applications
Equipped with excellent hydrocarbon solubility, the lithium hydride surrogate 1‐lithium‐2‐tert‐butyl‐1,2‐dihydropyridine (1tLi) functions as a precatalyst to convert Me(2)NH⋅BH(3) to [NMe(2)BH(2)](2) (89 % conversion) under competitive conditions (2.5 mol %, 60 h, 80 °C, toluene solvent) to that of...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2017
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5820744/ https://www.ncbi.nlm.nih.gov/pubmed/28940713 http://dx.doi.org/10.1002/chem.201703609 |