Chiral Ag(23) nanocluster with open shell electronic structure and helical face-centered cubic framework

We report the synthesis and crystal structure of a nanocluster composed of 23 silver atoms capped by 8 phosphine and 18 phenylethanethiolate ligands. X-ray crystallographic analysis reveals that the kernel of the Ag nanocluster adopts a helical face-centered cubic structure with C(2) symmetry. The t...

Descripción completa

Detalles Bibliográficos
Autores principales: Liu, Chao, Li, Tao, Abroshan, Hadi, Li, Zhimin, Zhang, Chen, Kim, Hyung J., Li, Gao, Jin, Rongchao
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2018
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5821857/
https://www.ncbi.nlm.nih.gov/pubmed/29467372
http://dx.doi.org/10.1038/s41467-018-03136-9

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5821857/
https://www.ncbi.nlm.nih.gov/pubmed/29467372
http://dx.doi.org/10.1038/s41467-018-03136-9

Ejemplares similares