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Modular Access to Azepines by Directed Carbonylative C–C Bond Activation of Aminocyclopropanes
[Image: see text] A modular Rh-catalyzed entry to azepines is outlined. Under a CO atmosphere, protecting group directed C–C bond activation of aminocyclopropanes provides rhodacyclopentanones. These intermediates are effective for intramolecular C–H metalation of either an N-aryl or N-vinyl unit en...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical
Society
2018
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5834216/ https://www.ncbi.nlm.nih.gov/pubmed/29461050 http://dx.doi.org/10.1021/jacs.7b13087 |