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Resolving a Reactive Organometallic Intermediate from Dynamic Directing Group Systems by Selective C−H Activation

Catalyst discovery from systems of potential precursors is a challenging endeavor. Herein, a new strategy applying dynamic chemistry to the identification of catalyst precursors from C−H activation of imines is proposed and evaluated. Using hydroacylation of imines as a model reaction, the selection...

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Detalles Bibliográficos
Autores principales: Schaufelberger, Fredrik, Timmer, Brian J. J., Ramström, Olof
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5836886/
https://www.ncbi.nlm.nih.gov/pubmed/29149517
http://dx.doi.org/10.1002/chem.201705273