Cargando…

Reagent-controlled regiodivergent ring expansions of steroids

Ring expansion provides a powerful way of introducing a heteroatom substituent into a carbocyclic framework. However, such reactions are often limited by the tendency of a given substrate to afford only one of the two rearrangement products or fail to achieve high selectivity at all. These limitatio...

Descripción completa

Detalles Bibliográficos
Autores principales: Charaschanya, Manwika, Aubé, Jeffrey
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5838248/
https://www.ncbi.nlm.nih.gov/pubmed/29507290
http://dx.doi.org/10.1038/s41467-018-03248-2