Visible‐Light‐Mediated Decarboxylative Radical Additions to Vinyl Boronic Esters: Rapid Access to γ‐Amino Boronic Esters

The synthesis of alkyl boronic esters by direct decarboxylative radical addition of carboxylic acids to vinyl boronic esters is described. The reaction proceeds under mild photoredox catalysis and involves an unprecedented single‐electron reduction of an α‐boryl radical intermediate to the correspon...

Descripción completa

Detalles Bibliográficos
Autores principales: Noble, Adam, Mega, Riccardo S., Pflästerer, Daniel, Myers, Eddie L., Aggarwal, Varinder K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2018
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5838549/
https://www.ncbi.nlm.nih.gov/pubmed/29316095
http://dx.doi.org/10.1002/anie.201712186

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5838549/
https://www.ncbi.nlm.nih.gov/pubmed/29316095
http://dx.doi.org/10.1002/anie.201712186

Ejemplares similares