Cargando…

Alkene 1,2‐Difunctionalization by Radical Alkenyl Migration

Transition‐metal‐free radical α‐perfluoroalkylation with the accompanying vicinal β‐alkenylation of unactivated alkenes is presented. These radical cascades proceed by means of 1,4‐ or 1,5‐alkenyl migration by electron catalysis on readily accessed allylic alcohols. The reactions comprise a regiosel...

Descripción completa

Detalles Bibliográficos
Autores principales: Tang, Xinjun, Studer, Armido
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5838557/
https://www.ncbi.nlm.nih.gov/pubmed/29165859
http://dx.doi.org/10.1002/anie.201710397