Indium- and Zinc-Mediated Acyloxyallylation of Protected and Unprotected Aldotetroses—Revealing a Pronounced Diastereodivergence and a Fundamental Difference in the Performance of the Mediating Metal

[Image: see text] The acyloxyallylation of unprotected aldoses was first demonstrated more than a decade ago as a potentially elegant two-carbon homologation of reducing sugars (upon ozonolysis); however, its application in real case syntheses remained scarce. Following up on such a successful showc...

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Detalles Bibliográficos
Autores principales: Draskovits, Markus, Stanetty, Christian, Baxendale, Ian R., Mihovilovic, Marko D.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2018
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5838623/
https://www.ncbi.nlm.nih.gov/pubmed/29369620
http://dx.doi.org/10.1021/acs.joc.7b03063

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5838623/
https://www.ncbi.nlm.nih.gov/pubmed/29369620
http://dx.doi.org/10.1021/acs.joc.7b03063

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