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Indium- and Zinc-Mediated Acyloxyallylation of Protected and Unprotected Aldotetroses—Revealing a Pronounced Diastereodivergence and a Fundamental Difference in the Performance of the Mediating Metal
[Image: see text] The acyloxyallylation of unprotected aldoses was first demonstrated more than a decade ago as a potentially elegant two-carbon homologation of reducing sugars (upon ozonolysis); however, its application in real case syntheses remained scarce. Following up on such a successful showc...
Autores principales: | Draskovits, Markus, Stanetty, Christian, Baxendale, Ian R., Mihovilovic, Marko D. |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical
Society
2018
|
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5838623/ https://www.ncbi.nlm.nih.gov/pubmed/29369620 http://dx.doi.org/10.1021/acs.joc.7b03063 |
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