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Relevance of Orbital Interactions and Pauli Repulsion in the Metal–Metal Bond of Coinage Metals

[Image: see text] The importance of relativity and dispersion in metallophilicity has been discussed in numerous studies. The existence of hybridization in the bonding between closed shell d(10)–d(10) metal atoms has also been speculated, but the presence of attractive MO interaction in the metal–me...

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Detalles Bibliográficos
Autores principales: Brands, Maria B., Nitsch, Jörn, Guerra, Célia Fonseca
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2018
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5842375/
https://www.ncbi.nlm.nih.gov/pubmed/29431436
http://dx.doi.org/10.1021/acs.inorgchem.7b02994