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Role of σ,π-Digold(I) Alkyne Complexes in Reactions of Enynes
[Image: see text] Gold(I) acetylide and σ,π-digold(I) alkyne complexes derived from one prototypical 1,6-enyne and from 7-ethynyl-1,3,5-cycloheptatriene have been prepared and structurally characterized. Their possible role in gold(I)-catalyzed cycloisomerizations has been studied by experiment and...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American
Chemical Society
2017
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5850095/ https://www.ncbi.nlm.nih.gov/pubmed/29551852 http://dx.doi.org/10.1021/acs.organomet.7b00668 |