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Electrochemical Corey–Winter reaction. Reduction of thiocarbonates in aqueous methanol media and application to the synthesis of a naturally occurring α-pyrone

An electrochemical version of the Corey–Winter reaction was developed giving excellent results in aqueous methanol media (MeOH/H(2)O (80:20) with AcOH/AcONa buffer 0.5 M as supporting electrolyte), using a reticulated vitreous carbon as cathode in a divided cell. The electrochemical version is much...

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Detalles Bibliográficos
Autores principales: López-López, Ernesto Emmanuel, Pérez-Bautista, José Alvano, Sartillo-Piscil, Fernando, Frontana-Uribe, Bernardo A
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5852465/
https://www.ncbi.nlm.nih.gov/pubmed/29623116
http://dx.doi.org/10.3762/bjoc.14.41