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Electrochemical Corey–Winter reaction. Reduction of thiocarbonates in aqueous methanol media and application to the synthesis of a naturally occurring α-pyrone
An electrochemical version of the Corey–Winter reaction was developed giving excellent results in aqueous methanol media (MeOH/H(2)O (80:20) with AcOH/AcONa buffer 0.5 M as supporting electrolyte), using a reticulated vitreous carbon as cathode in a divided cell. The electrochemical version is much...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Beilstein-Institut
2018
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5852465/ https://www.ncbi.nlm.nih.gov/pubmed/29623116 http://dx.doi.org/10.3762/bjoc.14.41 |