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Thiosemicarbazone organocatalysis: tetrahydropyranylation and 2-deoxygalactosylation reactions and kinetics-based mechanistic investigation

The first use of thiosemicarbazone-based organocatalysis was demonstrated on both tetrahydropyranylation and 2-deoxygalactosylation reactions. The organocatalysts were optimised using kinetics-based selection. The best catalyst outperformed previously reported thiourea catalysts for tetrahydropyrany...

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Detalles Bibliográficos
Autores principales: Larsen, Dennis, Langhorn, Line M., Akselsen, Olivia M., Nielsen, Bjarne E., Pittelkow, Michael
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5853554/
https://www.ncbi.nlm.nih.gov/pubmed/29568444
http://dx.doi.org/10.1039/c7sc03366d