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The α-tertiary amine motif drives remarkable selectivity for Pd-catalyzed carbonylation of β-methylene C–H bonds
The selective C–H carbonylation of methylene bonds in the presence of traditionally more reactive methyl C–H and C(sp(2))–H bonds in α-tertiary amines is reported. The exceptional selectivity is driven by the bulky α-tertiary amine motif, which we hypothesise orientates the activating C–H bond proxi...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2017
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5855970/ https://www.ncbi.nlm.nih.gov/pubmed/29568467 http://dx.doi.org/10.1039/c7sc03876c |