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Effective stabilization of a planar phosphorus(iii) center embedded in a porphyrin-based fused aromatic skeleton
Organophosphorus(iii) compounds usually take on stable pyramidal structures with a large inversion barrier of 30–35 kcal mol(–1). In contrast, diphenylphosphine-fused Ni(ii) porphyrin, where the phosphorus atom is directly attached at the meso-position and embedded in a rigid skeleton, exhibits a co...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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Royal Society of Chemistry
2017
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5857933/ https://www.ncbi.nlm.nih.gov/pubmed/29568471 http://dx.doi.org/10.1039/c7sc03882h |