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A matrix of heterobimetallic complexes for interrogation of hydrogen evolution reaction electrocatalysts

Experimental and computational studies address key questions in a structure–function analysis of bioinspired electrocatalysts for the HER. Combinations of NiN(2)S(2) or [(NO)Fe]N(2)S(2) as donors to (η(5)-C(5)H(5))Fe(CO)(+) or [Fe(NO)(2)](+/0) generate a series of four bimetallics, gradually “soften...

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Detalles Bibliográficos
Autores principales: Ghosh, Pokhraj, Ding, Shengda, Chupik, Rachel B., Quiroz, Manuel, Hsieh, Chung-Hung, Bhuvanesh, Nattami, Hall, Michael B., Darensbourg, Marcetta Y.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5858031/
https://www.ncbi.nlm.nih.gov/pubmed/29619175
http://dx.doi.org/10.1039/c7sc03378h