The elusive abnormal CO(2) insertion enabled by metal-ligand cooperative photochemical selectivity inversion

Direct hydrogenation of CO(2) to CO, the reverse water–gas shift reaction, is an attractive route to CO(2) utilization. However, the use of molecular catalysts is impeded by the general reactivity of metal hydrides with CO(2). Insertion into M–H bonds results in formates (MO(O)CH), whereas the abnor...

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Detalles Bibliográficos
Autores principales: Schneck, Felix, Ahrens, Jennifer, Finger, Markus, Stückl, A. Claudia, Würtele, Christian, Schwarzer, Dirk, Schneider, Sven
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2018
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5862843/
https://www.ncbi.nlm.nih.gov/pubmed/29563551
http://dx.doi.org/10.1038/s41467-018-03239-3

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5862843/
https://www.ncbi.nlm.nih.gov/pubmed/29563551
http://dx.doi.org/10.1038/s41467-018-03239-3

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