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The elusive abnormal CO(2) insertion enabled by metal-ligand cooperative photochemical selectivity inversion
Direct hydrogenation of CO(2) to CO, the reverse water–gas shift reaction, is an attractive route to CO(2) utilization. However, the use of molecular catalysts is impeded by the general reactivity of metal hydrides with CO(2). Insertion into M–H bonds results in formates (MO(O)CH), whereas the abnor...
| Autores principales: | , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Nature Publishing Group UK
2018
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5862843/ https://www.ncbi.nlm.nih.gov/pubmed/29563551 http://dx.doi.org/10.1038/s41467-018-03239-3 |