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Observing enzyme ternary transition state analogue complexes by (19)F NMR spectroscopy
Ternary transition state analogue (TSA) complexes probing the isomerization of β-d-glucose 1-phosphate (G1P) into d-glucose 6-phosphate (G6P) catalyzed by catalytically active, fluorinated (5-fluorotryptophan), β-phosphoglucomutase (βPGM) have been observed directly by (19)F NMR spectroscopy. In the...
| Autores principales: | , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2017
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5863612/ https://www.ncbi.nlm.nih.gov/pubmed/29619190 http://dx.doi.org/10.1039/c7sc04204c |