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A competing, dual mechanism for catalytic direct benzene hydroxylation from combined experimental-DFT studies
A dual mechanism for direct benzene catalytic hydroxylation is described. Experimental studies and DFT calculations have provided a mechanistic explanation for the acid-free, Tp(x)Cu-catalyzed hydroxylation of benzene with hydrogen peroxide (Tp(x) = hydrotrispyrazolylborate ligand). In contrast with...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Royal Society of Chemistry
2017
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5863614/ https://www.ncbi.nlm.nih.gov/pubmed/29619184 http://dx.doi.org/10.1039/c7sc02898a |