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The harpooning mechanism as evidenced in the oxidation reaction of the Al atom
The harpooning mechanism has long been proposed for elementary reaction dynamics involving metals. It is characterized by an initial electron transfer (ET) process from the metal to the oxidant molecule. For the titled reaction Al + O(2), the ET distance can be predicted to be 2.6 Å by simply calcul...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2017
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5868079/ https://www.ncbi.nlm.nih.gov/pubmed/29619204 http://dx.doi.org/10.1039/c7sc03314a |