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Palladium-catalyzed regiodivergent hydroaminocarbonylation of alkenes to primary amides with ammonium chloride

Palladium-catalyzed hydroaminocarbonylation of alkenes for the synthesis of primary amides has long been an elusive aim. Here, we report an efficient catalytic system which enables inexpensive NH(4)Cl to be utilized as a practical alternative to gaseous ammonia for the palladium-catalyzed alkene-hyd...

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Detalles Bibliográficos
Autores principales: Gao, Bao, Zhang, Guoying, Zhou, Xibing, Huang, Hanmin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5868317/
https://www.ncbi.nlm.nih.gov/pubmed/29629107
http://dx.doi.org/10.1039/c7sc04054g