Beyond optical rotation: what's left is not always right in total synthesis

This work describes the application of vibrational (VCD) and electronic (ECD) circular dichroism spectroscopy to solve the longstanding debate around the absolute configuration of (+)-frondosin B (1). The absolute configuration of (+)-1 could confidently be assigned as (R) using these spectroscopic...

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Detalles Bibliográficos
Autores principales: Joyce, Leo A., Nawrat, Christopher C., Sherer, Edward C., Biba, Mirlinda, Brunskill, Andrew, Martin, Gary E., Cohen, Ryan D., Davies, Ian W.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2017
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5868320/
https://www.ncbi.nlm.nih.gov/pubmed/29629112
http://dx.doi.org/10.1039/c7sc04249c

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5868320/
https://www.ncbi.nlm.nih.gov/pubmed/29629112
http://dx.doi.org/10.1039/c7sc04249c

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