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Beyond optical rotation: what's left is not always right in total synthesis
This work describes the application of vibrational (VCD) and electronic (ECD) circular dichroism spectroscopy to solve the longstanding debate around the absolute configuration of (+)-frondosin B (1). The absolute configuration of (+)-1 could confidently be assigned as (R) using these spectroscopic...
Autores principales: | Joyce, Leo A., Nawrat, Christopher C., Sherer, Edward C., Biba, Mirlinda, Brunskill, Andrew, Martin, Gary E., Cohen, Ryan D., Davies, Ian W. |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Royal Society of Chemistry
2017
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5868320/ https://www.ncbi.nlm.nih.gov/pubmed/29629112 http://dx.doi.org/10.1039/c7sc04249c |
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