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Variations in the fuel structure control the rate of the back and forth motions of a chemically fuelled molecular switch

This work deals with the use of 2-cyano-2-arylpropanoic acids as chemical fuels for an acid–base operated molecular switch that consists of a Sauvage-type catenand composed of two identical macrocycles incorporating a phenanthroline unit. When used as a base promoter of the decarboxylation of propan...

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Detalles Bibliográficos
Autores principales: Biagini, Chiara, Albano, Simone, Caruso, Rachele, Mandolini, Luigi, Berrocal, José Augusto, Di Stefano, Stefano
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5869305/
https://www.ncbi.nlm.nih.gov/pubmed/29629086
http://dx.doi.org/10.1039/c7sc04123c