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Metal–organic layers stabilize earth-abundant metal–terpyridine diradical complexes for catalytic C–H activation
We report the synthesis of a terpyridine-based metal–organic layer (TPY-MOL) and its metalation with CoCl(2) and FeBr(2) to afford CoCl(2)·TPY-MOL and FeBr(2)·TPY-MOL, respectively. Upon activation with NaEt(3)BH, CoCl(2)·TPY-MOL catalyzed benzylic C–H borylation of methylarenes whereas FeBr(2)·TPY-...
Autores principales: | , , , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Royal Society of Chemistry
2017
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5869321/ https://www.ncbi.nlm.nih.gov/pubmed/29629082 http://dx.doi.org/10.1039/c7sc03537c |