Metal–organic layers stabilize earth-abundant metal–terpyridine diradical complexes for catalytic C–H activation

We report the synthesis of a terpyridine-based metal–organic layer (TPY-MOL) and its metalation with CoCl(2) and FeBr(2) to afford CoCl(2)·TPY-MOL and FeBr(2)·TPY-MOL, respectively. Upon activation with NaEt(3)BH, CoCl(2)·TPY-MOL catalyzed benzylic C–H borylation of methylarenes whereas FeBr(2)·TPY-...

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Detalles Bibliográficos
Autores principales: Lin, Zekai, Thacker, Nathan C., Sawano, Takahiro, Drake, Tasha, Ji, Pengfei, Lan, Guangxu, Cao, Lingyun, Liu, Shubin, Wang, Cheng, Lin, Wenbin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2017
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5869321/
https://www.ncbi.nlm.nih.gov/pubmed/29629082
http://dx.doi.org/10.1039/c7sc03537c

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